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Water Acidity The simplest definition is to use the pH. In this case, "acidity" is related to proton concentration. pH = - log10[H+] However, the acidic proton may be attached to the acid. The acid equilibrium is HA « H+ + A- The acid, HA, looses a proton, H+, to become the conjugate base, A-. Mathematically, this equilibrium is given by the equilibrium equation
The "acid strength" is characterized by the pKA given by the equation pKA = - log10 KA Acids with pKA less than 7 are said to be acidic (strong relative to water) while those with pKA greater than 7 are said to be basic (weak relative to water). Water acidity found by titration is used to determine the total concentration of protons. If one titrates water with a strong base, the proton may react to form water OH- + HA « H2O + A- The pH at the end-point of the titration is related to pKA by
Titration to a methyl orange indicator end-point (pKIn = 4.3) is used to determine the strong mineral acid content. Titration to a phenolphthalein indicator end-point (pKIn = 8.2) determines total acids. In summary, there are three ways to characterize water acidity.
This page edited Thursday, December 21, 2006 |
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This page was last edited Thursday, December 21, 2006 |