Water Acidity

The simplest definition is to use the pH. In this case, "acidity" is related to proton concentration.

pH = - log10[H+]

However, the acidic proton may be attached to the acid. The acid equilibrium is

HA « H+ + A-

The acid, HA, looses a proton, H+, to become the conjugate base, A-.

Mathematically, this equilibrium is given by the equilibrium equation

The "acid strength" is characterized by the pKA given by the equation

pKA = - log10 KA

Acids with pKA less than 7 are said to be acidic (strong relative to water) while those with pKA greater than 7 are said to be basic (weak relative to water).

Water acidity found by titration is used to determine the total concentration of protons.

If one titrates water with a strong base, the proton may react to form water

OH- + HA « H2O + A-

The pH at the end-point of the titration is related to pKA by

Titration to a methyl orange indicator end-point (pKIn = 4.3) is used to determine the strong mineral acid content.

Titration to a phenolphthalein indicator end-point (pKIn = 8.2) determines total acids.

In summary, there are three ways to characterize water acidity.

  1. through a measurement of pH
  2. with methyl orange end point titration with base to determine strong mineral acidity
  3. with phenolphthalein indicator end point base titration to determine total acids

This page edited Thursday, December 21, 2006

This page was last edited Thursday, December 21, 2006